FES Funded ProjectsOutputs
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Separation Of Oil Sands Process Water Organics And Inorganics And Examination Of Their Acute Toxicity Using Standard In-Vitro BioassaysT10-P04, T10-P04E University of Alberta | Publication | 2019-08-01 | | An Integrated Treatment System For Sustainable Clean WaterDevelopment of interdisciplinary research on integrated treatment approaches for energy systems process water. Submitted NOI to New Frontiers Research Fund Transformation program. T10-P04, T10-P04E, T10-P04F, T10-P04H University of Alberta | Activity | 2019-12-16 | Naeth, M., Gamal El-Din, M., Adamowicz, V., Chang, S., Bipro Dhar, Stafford, J., "Patrick Hanington ", "Maricor Arlos ", "Xiaoli Fan ", "Mark Servos ", "Dion Dionysiou ", "Sandra Contreras " | Fate Of Dissolved Organics And Generated Sulfate Ions During Biofiltration Oil Sands Process Water Pretreated With Sulfate Radical advanced Oxidation ProcessT10-P04, T10-P04E University of Alberta | Publication | 2023-01-11 | | Electrocatalytic Activation Of Peroxomonosulfate (PMS) Under Aerobic Condition For The Remediation Of Oil Sands Process Water: Insight Into One-Pot Synergistic Coupling Of PMS Electro-Activation And Heterogeneous Electro-Fenton ProcessesT10-P04, T10-P04E University of Alberta | Publication | 2024-01-14 | | Examining The Immunotoxicity Of Oil Sands Process Affected Waters Using A Human Macrophage Cell LineT10-P04, T10-P04E University of Alberta | Publication | 2023-11-28 | | UVA LED-Assisted Breakdown Of Persulfate Oxidants For The Treatment Of Real Oil Sands Process Water: Removal Of Naphthenic Acids And Evaluation Of Residual ToxicityT10-P04, T10-P04E University of Alberta | Publication | 2024-01-12 | Isaac Sanchez Montes, Hadi Mokarizadeh, "Sunanda Paul ", "Kareem Moghrabi ", Nora A S Hussain, Pamela Chelme-Ayala, Stafford, J., Marcos R V Lanza, Gamal El-Din, M. | Novel Microbe-Based Toxicity Assessment Tools For Examining Oil Sands Processed WatersT10-P04, T10-P04E University of Alberta | Activity | 2023-11-13 | | Engineered Biochar-Iron Nanocomposite for Efficient Peroxymonosulfate Activation: Degradation of Naphthenic Acids, Toxicity Evaluation, and Economic AssessmentAbstract
This paper explores the use of engineered biochar coupled with zero-valent iron (Fe0) and peroxymonosulfate (PMS) for the degradation of naphthenic acids (NAs) and fluorophore organic compounds (FOCs) in real oil sands process water (OSPW). Immobilizing Fe0 on biochar, a stable, porous carbon-based material, enhanced catalyst stability and degradation efficiency. Experimental results demonstrated significant removal of FOCs, classical, and oxidized NAs. Notably, 1 g/L of catalyst achieved ∼80 % removal of O2-NAs within 120 min, primarily through the generation of sulfate and hydroxyl radicals. To assess the toxicity of treated OSPW, cell-based immunotoxicity assays were conducted by measuring pro-inflammatory cytokine secretion in human and mouse macrophage cells. Treated OSPW exhibited a significant reduction in cytokine secretion, indicating lower immunotoxicity. Additionally, bacterial toxicity tests using Staphylococcus warneri revealed a reduced inhibitory effect on bacterial growth post-treatment. A comprehensive economic assessment benchmarked this method against various advanced oxidation processes (AOPs), demonstrating its cost-effectiveness, particularly when compared to light-based AOPs. These findings highlight Fe0-biochar-PMS treatment as a sustainable and efficient approach for mitigating OSPW toxicity, offering a viable solution for improved wastewater management in oil sands operations.T10-P04 University of Alberta | Publication | 2025-05-05 | |
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