| Analysis of the products and kinetic rates of methane thermal decomposition. Part II: Numerical modelsNot a formal publication, so that results can be published in a Journal without copyright issues
University of Alberta, Carleton Unviersity | Publication | 2019-05-16 | Ambuj Punia, James Kole William Tatum, Olfert, J., Kostiuk, L., Secanell, M. |
| Analysis of the products and kinetic rates of methane thermaldecomposition. Part I: Experimental apparatus University of Alberta, Carleton Unviersity | Publication | 2019-05-16 | James Kole William Tatum, Ambuj Punia, Secanell, M., Kostiuk, L., Olfert, J. |
| Kinetics of methane pyrolysis: An optimized mechanismNot a formal publication, so that results can be published in a Journal without copyright issues
University of Alberta, Carleton Unviersity | Publication | 2020-02-19 | Ambuj Punia, James Kole William Tatum, Olfert, J., Kostiuk, L., Secanell, M. |
| Preliminary experimental study of methane decarbonization using a laminar premixed flameNot a formal publication, so that results can be published in a Journal without copyright issues
University of Alberta, Carleton Unviersity | Publication | 2017-05-18 | Farjad Falahati, Mohammad Afroughi, Olfert, J., Kostiuk, L. |
| Properties of carbon particles generated by methane decarbonization in oxygen deficient gas streamsNot a formal publication, so that results can be published in a Journal without copyright issues
Carleton Unviersity, University of Alberta | Publication | 2018-09-07 | Mohammad Afroughi, Farjad Falahati, Kostiuk, L., Olfert, J. |
| Biobattery concept: Decentralized production of fuel from forest biomass, agriculture residue and municipal solid waste University of Alberta, Carleton Unviersity | Activity | 2018-03-14 | Adetoyese Oyedun, Vinoj Kurian, Wasel-ur Rahman, Manjot Gill, Kumar, A., Gupta, R., Kostiuk, L., "Andreas Hornung" |
| Decentralized use of forest biomass, agricultural residue, and municipal solid waste through the biobattery concept University of Alberta, Carleton Unviersity | Activity | 2017-11-06 | Adetoyese Oyedun, Vinoj Kurian, Kumar, A., Gupta, R., Kostiuk, L., "Andreas Hornung" |
| Nanoparticle Emission Characteristics during Methane Pyrolysis in a Laminar Premixed Flame Carleton Unviersity, University of Alberta | Activity | 2018-04-16 | Mohammad Afroughi, Farjad Falahati, Kostiuk, L., Olfert, J. |
| Dataset of methane pyrolysis products in a batch reactor as a function of time at high temperatures and pressures Carleton Unviersity, University of Alberta | Publication | 2023-04-01 | James Kole William Tatum, Ambuj Punia, Kostiuk, L., Secanell, M., Olfert, J. |
| Experimental and numerical analysis of a methane thermal decomposition reactor Carleton Unviersity, University of Alberta | Publication | 2017-11-05 | "Derek Paxman", "S Trottier", M R Flynn, Kostiuk, L., Secanell, M. |
| Properties of carbon black produced by the thermal decomposition of methane in the products of premixed flamesThe thermal decomposition of methane is a technique used to manufacture hydrogen gas and carbon black. The physical properties of carbon black produced by the thermal decomposition of methane (TDM) in the O2-deficient gas products of two premixed flames (propane- or methane- air) were investigated under different flow rates of decomposing methane injection (0.5–5 SLPM). An inverted burner was designed to provide a fuel-rich, laminar premixed flame, to produce hot gas into which methane was injected to thermally decompose inside a reactor. Particles from TDM were extracted by a nitrogen dilution system at the immediate exit of the reaction chamber, where another branch of the exhaust was dried and directed to a gas chro- matograph. The carbon black particles were characterized by size resolved number concentra- tion, mass concentration, effective density, volatility, and internal mixing state using different arrangements of a differential mobility analyzer, catalytic denuder, centrifugal particle mass analyzer, and condensation particle counter, as well as by morphology and primary particle size using transmission electron microscopy. A bimodal number-size distribution was observed at all conditions with count median diameters (CMDs) less than 58 nm and 21 nm when using pro- pane- or methane-air premixed flames as the heat source, respectively. Higher number con- centrations and mass concentrations with larger CMDs were achieved under lower flow rates of decomposing methane injection. For a given flow rate of decomposition methane, mass con- centration and CMD increased significantly when using propane as the fuel, compared to the methane fuel. The size segregated mass fraction of internally mixed volatile content in particles was similar for both heat sources, showing a roughly constant fraction of volatile material in particles produced by the decomposition of 0.5 and 5 SLPM of methane (10%–30%) but a measurably larger fraction (55%–30%) with a decreasing trend as a function of particle size from the decomposition of 1 SLPM of methane. The effective density of denuded particles was similar, but slightly higher, than the effective density of soot from a wide range of internal combustion engines. A higher denuded effective density was observed in the particles with higher volatile contents (particles from decomposition of 1 SLPM of methane), suggesting the restructuring of carbon black into more compact clusters due to excessive volatile condensation. TEM analysis revealed some similarity between the produced carbon black and engine soot in terms of mor- phology and primary particle diameter (both below 40 nm). Beside the carbon black properties, the efficiency of TDM in this configuration was also investigated by evaluation of methane de- struction efficiency, as well as carbon black and hydrogen production efficiencies, based on the product gas composition and the particle mass concentration. It was found that longer residence times corresponding to lower flow rates resulted in higher conversion efficiencies in terms of methane destruction efficiency (maximum of ∼95%), hydrogen production efficiency (maximum of 80%), and carbon black production efficiency (maximum of 1%). It was concluded that the significantly low efficiency of carbon black production is due to the high amount of CO forma- tion, likely through the gasification process. Carleton Unviersity, University of Alberta | Publication | 2019-02-23 | Mohammad Afroughi, Farjad Falahati, Kostiuk, L., Olfert, J. |
